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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes

A Study of Molecular and Electronic Structure

  • Book
  • © 2012

Overview

  • Nominated by the University of Erlangen-Nuremberg as an outstanding PhD thesis
  • Synthesis, structural and spectroscopic characterization of high valent iron nitride complexes
  • Addresses the search for iron complexes in high oxidation states
  • Includes supplementary material: sn.pub/extras

Part of the book series: Springer Theses (Springer Theses)

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Table of contents (6 chapters)

Keywords

About this book

Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

Authors and Affiliations

  • Erlangen-Nuremberg, Department of Chemistry and Pharmacy, Friedrich-Alexander-University, Erlangen, Germany

    Carola S. Vogel

Bibliographic Information

  • Book Title: High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes

  • Book Subtitle: A Study of Molecular and Electronic Structure

  • Authors: Carola S. Vogel

  • Series Title: Springer Theses

  • DOI: https://doi.org/10.1007/978-3-642-27254-7

  • Publisher: Springer Berlin, Heidelberg

  • eBook Packages: Chemistry and Materials Science, Chemistry and Material Science (R0)

  • Copyright Information: Springer-Verlag Berlin Heidelberg 2012

  • Hardcover ISBN: 978-3-642-27253-0Published: 04 February 2012

  • Softcover ISBN: 978-3-662-50905-0Published: 23 August 2016

  • eBook ISBN: 978-3-642-27254-7Published: 03 February 2012

  • Series ISSN: 2190-5053

  • Series E-ISSN: 2190-5061

  • Edition Number: 1

  • Number of Pages: XVIII, 132

  • Topics: Inorganic Chemistry, Catalysis, Enzymology

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